4-{[1-(4-Bromophenyl)ethyl]aminomethyl}phenol
نویسنده
چکیده
The title compound, C(15)H(16)BrNO, obtained from a two-step reaction, was prepared for use in transition metal chemistry as a phenolic ligand with bulky substituents. Inter-molecular N-H⋯O and O-H⋯N hydrogen bonds are present in the crystal structure.
منابع مشابه
Crystal structure of 4-((1E)-1-{(2Z)-2-[4-(4-bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)phenol hemihydrate
In the title compound, C23H18BrN3OS·0.5H2O, the bromo-phenyl, phenyl and phenol rings make dihedral angles of 46.5 (1), 66.78 (8) and 15.4 (2)°, respectively, with the mean squares plane of the thia-zol-idene ring. In the crystal, the lattice water mol-ecule is hydrogen bonded to the phenol group and makes a weaker O-H⋯N connection to an inversion-related mol-ecule, forming a ring while weak pa...
متن کاملCrystal structure of 2-{(R)-[1-(4-bromophenyl)ethyl]iminomethyl}-4-(phenyldiazenyl)phenol, a chiral photochromic Schiff base
The title chiral photochromic Schiff base compound, C21H18BrN3O, was synthesized from (R)-(+)-1-(4-bromo-phen-yl)ethyl-amine and the salicyl-aldehyde of an azo-benzene derivative. The mol-ecule corresponds to the phenol-imine tautomer, the C=N and N-C bond distances being 1.285 (3) and 1.470 (3) Å, respectively. The diazenyl group adopts a trans form, with an N=N distance of 1.256 (3) Å. The hy...
متن کامل[(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol. Corrigendum
The title and the chemical diagram of the paper by Zhang, Peng, Gao & Fan [Acta Cryst. (2008), E64, o403] are corrected.[This corrects the article DOI: 10.1107/S1600536807055559.].
متن کامل[(2-{[3′,6′-Bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[1H-isoindole-1,9′-9H-xanthen]-2-yl}ethyl)aminomethyl]phenol
The title compound, C(35)H(38)N(4)O(3), was prepared as a spiro-lactam ring formation of rhodamine dye for comparison with a ring-opened form. The xanthene ring system is approximately planar. The dihedral angles formed by the spiro-lactam and phenol rings with the xanthene ring system are 85.7 and 109.4°, respectively. Each of the mol-ecules in the crystal structure contains one intra-molecula...
متن کامل2-[(Adamantan-1-yl)aminomethyl]-4-chlorophenol hemihydrate
In the title compound, C17H22ClNO·0.5H2O, the water mol-ecule O atom resides on a twofold rotation axis. In the organic mol-ecule, the phenol group forms an intra-molecular O-H⋯N hydrogen bond. In the crystal, pairs of organic mol-ecules are hydrogen bonded through bridging solvent water mol-ecules, forming chains along the b-axis direction.
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